Electrolytic capacitors are polarised and they must be connected the correct way round, at least one of their leads will be marked + or -. They are not damaged by heat when soldering.
There are two designs of electrolytic capacitors; axial where the leads are attached to each end (220μF in picture) and radial where both leads are at the same end (10μF in picture). Radial capacitors tend to be a little smaller and they stand upright on the circuit board.

It is easy to find the value of electrolytic capacitors because they are clearly printed with their capacitance and voltage rating. The voltage rating can be quite low (6V for example) and it should always be checked when selecting an electrolytic capacitor. If the project parts list does not specify a voltage, choose a capacitor with a rating which is greater than the project's power supply voltage. 25V is a sensible minimum for most battery circuits.